World Journal of Chemical Education. 2023, 11(3), 114-120
DOI: 10.12691/WJCE-11-3-15
Special Issue

Tracking Electrons - Colourful Insights into the Processes of Bipolar Electrochemistry with Polypyrrole

Dominik Quarthal1 and Marco Oetken1,

1Department of Chemistry, Physics, Technology and their teaching methodologies, University of Education Freiburg, Kunzenweg 21, 79117 Freiburg, Germany,

Pub. Date: September 27, 2023
(This article belongs to the Special Issue Innovative experiments in chemistry didactics in Germany)

Cite this paper

Dominik Quarthal and Marco Oetken. Tracking Electrons - Colourful Insights into the Processes of Bipolar Electrochemistry with Polypyrrole. World Journal of Chemical Education. 2023; 11(3):114-120. doi: 10.12691/WJCE-11-3-15

Abstract

The following article is intended to highlight the importance and usefulness of bipolar electrochemistry for science and for school and university teaching. In addition, a suitable explanation of the phenomena that take place on the basis of bipolar electrochemistry will be presented and visualised and confirmed by means of the different colours of the oxidation states of polypyrrole.

Keywords

bipolar electrochemistry, polymers,polypyrrole, water electrolysis

Copyright

Creative CommonsThis work is licensed under a Creative Commons Attribution 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

References

[1]  Fosdick, S. E., Knust, K. N., Scida, K., Crooks, R. M. (2013). Bipolare Elektrochemie. Angew. Chem. 125/40, 10632–10651.
 
[2]  Hermann, A., Chaudhuri, T., Spagnol, P. (2005). Bipolar plates for PEM fuel cells: A review. International Journal of Hydrogen Energy 30/12, 1297–1302.
 
[3]  Shida, N., Zhou, Y., Inagi, S. (2019). Bipolar Electrochemistry: A Powerful Tool for Electrifying Functional Material Synthesis. Accounts of chemical research 52/9, 2598–2608.
 
[4]  Salinas, G., Arnaboldi, S., Bouffier, L., Kuhn, A. (2022). Recent Advances in Bipolar Electrochemistry with Conducting Polymers. ChemElectroChem 9/1.
 
[5]  Christiane Köllner (2018). Was ist eine Bipolarbatterie? https://www.springerprofessional.de/batterie/elektromobilitaet/was-ist-eine-bipolarbatterie-/16315822 (last access date 12.03.23).
 
[6]  Baden-Württemberg, Ministerium für Kultus, Jugend und Sport (2016). Bildungsplan des Gymnasiums. Bildungsplan 2016 - Chemie. https://www.bildungsplaene-bw.de/site/bildungsplan/get/documents/lsbw/export-pdf/depot-pdf/ALLG/BP2016BW_ALLG_GYM_CH.pdf (letzter Zugriff am 10.03.23).
 
[7]  Sommer, K. A., Wambach-Laicher, J., Pfeifer, P. (Hrsg.) (2019). Konkrete Fachdidaktik Chemie. Grundlagen für das Lernen und Lehren im Chemieunterricht, 2. Aufl. Aulis, Seelze.
 
[8]  Koch, K. (2020). Ions and electric current in bipolar water electrolysis. CHEMKON 27/2, 92–95.
 
[9]  Kurzweil, P., Dietlmeier, O. (2018). Elektrochemische Speicher. Superkondensatoren, Batterien, Elektrolyse-Wasserstoff, Rechtliche Rahmenbedingungen, 2. Aufl. Springer Fachmedien Wiesbaden, Wiesbaden.
 
[10]  Ansari, R. (2006). Polypyrrole Conducting Electroactive Polymers: Synthesis and Stability Studies. E-Journal of Chemistry 3/4, 186–201.
 
[11]  C. Wagner, F.J., M. Oetken (2016). Leitfähige Polymere. elektrochemische Alleskönner. PdN-ChiS 65/3, 34–43.
 
[12]  Polypyrrole: a conducting polymer; it’s synthesis, properties and applications. Russian Chemical Reviews, Volume 66, Issue 5, pp. 443-457 (1997).