World Journal of Chemical Education. 2018, 6(1), 72-77
DOI: 10.12691/WJCE-6-1-11
Special Issue

Electrochemical Synthesis of Coin Metal Nanoparticles in School Chemistry Education

Elena von Hoff1, Stefanie Waitz1, Felix Kollenda1 and Thomas Waitz1,

1Department of Chemistry Education, Georg-August-University Göttingen, Germany

Pub. Date: January 27, 2018

Cite this paper

Elena von Hoff, Stefanie Waitz, Felix Kollenda and Thomas Waitz. Electrochemical Synthesis of Coin Metal Nanoparticles in School Chemistry Education. World Journal of Chemical Education. 2018; 6(1):72-77. doi: 10.12691/WJCE-6-1-11

Abstract

Within this article we present the synthesis of coin metal nanoparticles and nanoporous surfaces by cathodic corrosion as school experiments. We further present two experiments utilizing the obtained materials as catalysts; the catalytic decomposition of hydrogen peroxide and the platinum catalyzed chemiluminescence of lucigenin.

Keywords

nanomaterials, catalysis, school chemistry

Copyright

Creative CommonsThis work is licensed under a Creative Commons Attribution 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

References

[1]  Yanson, A. I., Rodriguez, P., Garcia-Araez, N., Mom, R. V., Tichelaar, F. D., Koper, M. T. M., „Cathodic Corrosion: A Quick, Clean, and Versatile Method for the Synthesis of Metallic Nanoparticles,” Angew. Chem. Int. Ed., 50. 6346-6350. May 2011.
 
[2]  Rodriguez, P., Tichelaar, F. D., Koper, M. T. M., Yanson, A. I., “Cathodic Corrosion as a Facile and Effective Method To Prepare Clean Metal Alloy Nanoparticles,” J. Am. Chem. Soc., 133. 17626-17629. Oct. 2011.
 
[3]  Weiss, J, “The catalytic decomposition of hydrogen peroxide on different metals,” Trans. Faraday Soc., 31. 1547-1557. Jul. 1935.
 
[4]  McKee, D. W., “Catalytic Decomposition of Hydrogen Peroxide by Metals and Alloys of the Platinum Group,” J. Catalysis, 14. 355-364. Aug. 1969.
 
[5]  Maskiewicz, R., Sogah, D., Bruice, T. C., “Chemiluminescent Reactions of Lucigenin. 2. Reactions of Lucigenin with Hydroxide Ion and Other Nucleophiles,” J. Am. Chem. Soc., 101. 5355-5364. Aug. 1979.
 
[6]  Duan, C. F., Cui, H., “Time-tunable autocatalytic lucigenin chemiluminescence initiated by platinum nanoparticles and ethanol,” Chem. Commun., (18). 2574-2576. May 2009.