World Journal of Chemical Education. 2018, 6(6), 230-238
DOI: 10.12691/WJCE-6-6-1
Case Report

Advanced Treatment of Chemical Equilibria in the Prediction of the Time of Dissolution of Limestone in a Water Body by the Action of Acid Rain

Vitor Paulo Andrade da Silva1, , Pablo Gordiano A. Barbosa2, Thiago Coutinho Medeiros1 and Ronaldo Ferreira do Nascimento1,

1Departamento de Química Analítica e Físico-Química, Universidade Federal do Ceará, Fortaleza

2Instituto Federal de Educação, Ciência e Tecnologia do Ceará

Pub. Date: December 18, 2018

Cite this paper

Vitor Paulo Andrade da Silva, Pablo Gordiano A. Barbosa, Thiago Coutinho Medeiros and Ronaldo Ferreira do Nascimento. Advanced Treatment of Chemical Equilibria in the Prediction of the Time of Dissolution of Limestone in a Water Body by the Action of Acid Rain. World Journal of Chemical Education. 2018; 6(6):230-238. doi: 10.12691/WJCE-6-6-1

Abstract

In this study is reported an interdisciplinary approach to teaching chemistry using case studies seeking to stimulate the students in the learning process as well as to develop their critical thinking. The focuses were in chemical multiple equilibrium from an environmental problem based on the quantitative assessment of the dissolution process of limestone sediment containing in a water body by the action of acid rain and increasing of the CO2 atmospheric concentration. The variables considered were pluviometric average, CO2, SO2 and NO2 levels in the atmosphere as well as their dissolution equilibria and CaCO3 sediment precipitation. This study is an important teaching tool that can be applied in undergraduate and postgraduate chemistry courses with emphasis in Analytical and Environmental Chemistry, engaging students in active discussion about issues and problems inherent to practical applications.

Keywords

environmental chemistry, computer-based learning, atmospheric chemistry, computational chemistry, acid-base chemical equilibrium

Copyright

Creative CommonsThis work is licensed under a Creative Commons Attribution 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

References

[1]  Levie, R., “On Teaching Ionic Activity Effects: What, When, and Where?”, J. Chem. Educ., 82, 878-884, 2005.
 
[2]  Becker, N. M., Rupp, C. A. & Brandriet, A., “Engaging students in analyzing and interpretating data to construct mathematical models: An analysis of students' reasoning in a method of initial rates task”, Chem. Educ. Res. Pract., 18, 4, 798-810, 2017.
 
[3]  Rogers, F., Huddle, P.A. and White, M.W., “Simulations for Teaching Chemical Equilibrium”, J. Chem. Educ., 77, 920-926, 2000.
 
[4]  Gil, V.M.S. and Paiva, J.C.M., “Using Computer Simulations To Teach Salt Solubility: The Role of Entropy in Solubility Equilibrium”, J. Chem. Educ., 83, 170-172, 2006.
 
[5]  Paolini, C. and Bhattacharjee, S., “Solving Chemical Equilibrium Problems Online”, J. Chem. Educ., 87, 456, 2010.
 
[6]  Baeza, B.J.J. and Coque, M.C.G.A., “Systematic Approach To Calculate the Concentration of Chemical Species in Multi-Equilibrium Problems”, J. Chem. Educ., 88, 169-173, 2011.
 
[7]  Zang, D.; Shen, J., “Disciplinary Foundations for Solving Interdisciplinary Scientific Problems”. I. J.Sci. Educ., 37, 15, 2555-2576, 2015.
 
[8]  Tabbutt, F.D., “Water: A Powerful Theme for an Interdisciplinary Course”, J.Chem. Educ., 77, 1594-1601, 2000.
 
[9]  Walczak, M.M., Lantz, J.M. and Well W., “A Case on Septic Systems and Well Water Requiring In-Depth Analysis and Including Optional Laboratory Experiments”, J. Chem. Educ., 81, 218-220, 2004.
 
[10]  Ducros, M., “Observation d’une pluie acide’”, J. Pharm. Chim. 3, 7, 273-277, 1845.
 
[11]  Smith, R.A., “On the air and rain of Manchester”, Mem. Manch. Lit. Philos. Soc. 10 (Series 2), 207-217. 1852.
 
[12]  Smith, R.A. Air and Rain: the Beginnings of a Chemical Climatology. Longmans, Green and Company, London, 1872.
 
[13]  Burns, D.A., Aherne, J., Gay, D.A., Lehmann, C., “Acid rain and its environmental effects: recent scientific advances”, Atmos. Environ., 146, 1-4, 2016.
 
[14]  Li Zong-Jie, Ling-Ling Song, Ma Jing-zhu, Yong-ge Li, “The characteristics changes of pH and EC of atmospheric precipitation and analysis on the source of acid rain in the source area of the Yangtze River from 2010 to 2015”. Atmosp. Environ., 156 61-69, 2017.
 
[15]  Driscoll, C.T., Driscoll, K.M., Mitchell M.J. and Raynal D.J. (2003). Effects of acidic deposition on forest and aquatic ecosystems in New York State. Environmental Pollution, 123, 327-336.
 
[16]  Burns, D.A., Aherne, J., Gay, D.A. and Lehmann, C.M.B., “Acid rain and its environmental effects: Recent scientific advances”, Atmosp. Environ., 146, 1-4, 2016.
 
[17]  Livingston, R.A., “Acid rain attack on outdoor sculpture in perspective”, Atmosp. Environ., 146, 332-345, 2016.
 
[18]  Singh, A. and Agrawal, M., “Acid rain and its ecological consequences”, J. Environ. Biol., 29, 15-24, 2008.
 
[19]  Ikuta, K., Suzuki, Y. and Kitamura, S., “Effects of low pH on the reproductive behavior of salmonid fishes”, Fish Physiol. Biochem., 28, 407, 2003.
 
[20]  Wright, R.F., Egil T.G., “Acid Precipitation: Changes in the Chemical Composition of Lakes”, Ambio, 5, 219-223, 1976.
 
[21]  Spiro, T.G. and Stigliani, W.M. Chemistry of the environment, Pearson, São Paulo, 2009.
 
[22]  Baird, C. and Cann, M. Química ambiental, Bookman, Porto Alegre, 2011.
 
[23]  Skoog, D. A.; West, D. M.; Holler, F. J.; Crouch, S. R.; Fundamentos de Química Analítica, 8 ed., Grassi, M. T., trad.; Pioneira Thomson Learning: São Paulo, 2006.
 
[24]  Girard, J. E. Princípios de Química Ambiental, LTC, Rio de Janeiro, 2016.
 
[25]  Koltholff, I.M., Bruckenstein, S. and Elving, P.J. Treatise on Analytical Chemistry, Interscience, New York, 1959.
 
[26]  Bard, A.J. Chemical Equilibrium. Harper & Row. New York, 1966.
 
[27]  Kolthoff, I.M., Sandell E. B., Meehan E. J., Bruckenstein, S. Quantitative Chemical Analysis, Macmillan Pub Co., London, 1969.
 
[28]  Tadano, Y.S., Mazza, A.R., Tomaz, E., “Modelagem da Dispersão de Poluentes Atmosféricos no Município de Paulínia (Brazil) Empregando o ISCST3”. Asoc. Arg. Mec. Comp., Buenos Aires. Argentina, 29, 8125-8148, 2010.
 
[29]  Harris, D.C. Análise Química Quantitativa, LTC, Rio de Janeiro, 2012.
 
[30]  Lenzi, E., Favero, L.O.B., Luchese, E. B. Introdução à Química da Água: Ciência, Vida e Sobrevivência, LTC, São Paulo, 2009.
 
[31]  Martins, C.R. and Andrade, J.B., “Química Atmosférica do Enxofre (IV): Emissões, Reações em Fase Aquosa e Impacto Ambiental”, Quím. Nova, 25, 259-272, 2002.
 
[32]  Bashkin, V. N. Environmental chemistry: Asian lessons, Springer Science & Business Media, 2003.
 
[33]  Ikuta K., Yada T., Kitamura S., Ito F., Yamagichi, M., Nishimura, T., Kaneko, T., Nagae, M., Ishimatsu, A., Iwata, M., “Effects of acidification on fish reproduction”, UJNR Technical Report, Kihei, Hawaii, 28, 39-45, 1999.
 
[34]  Sarno P. and Andrade, J. B., “Química Ambiental em ação: uma nova abordagem para tópicos de química relacionados com o ambiente”, Quím. Nova, 13, 213-221, 1990.