World Journal of Chemical Education. 2019, 7(1), 26-32
DOI: 10.12691/WJCE-7-1-4
Original Research

An Undergraduate Experiment Using Microwave-Assisted Synthesis of Metalloporphyrins: Characterization and Spectroscopic Investigations

Shaikha S. Al Neyadi1, Ahmed Alzamly1, Abdullah Al-Hemyari1, Ibrahim M. Tahir1, Saeed Al-Meqbali1, M. A. Ali Ahmad1 and Muna Bufaroosha1,

1Department of Chemistry, College of Science, UAE University, Al-Ain, UAE

Pub. Date: February 04, 2019

Cite this paper

Shaikha S. Al Neyadi, Ahmed Alzamly, Abdullah Al-Hemyari, Ibrahim M. Tahir, Saeed Al-Meqbali, M. A. Ali Ahmad and Muna Bufaroosha. An Undergraduate Experiment Using Microwave-Assisted Synthesis of Metalloporphyrins: Characterization and Spectroscopic Investigations. World Journal of Chemical Education. 2019; 7(1):26-32. doi: 10.12691/WJCE-7-1-4

Abstract

The effectiveness of microwave-assisted synthesis of 5,10,15,20-tetraphenylporphyrin and its corresponding to metal complexes of (Bi (III), Zn (II) and Ni (II)) are described. Moreover, the synthesized metalloporphyrins that were obtained with reasonable yields were characterized using UV-vis, 1H-NMR and IR.

Keywords

porphyrins, metalloporphyrins, microwave synthesis

Copyright

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References

[1]  Ferrio, M.A., Relational typologies in couples suffering from psychogenic infertility. Ann Ist Super Sanita, 1992. 28(2): p. 291-3.
 
[2]  Xiang, Z. and K.P. Ravindra, Porphyrin-Carbohydrate Conjugates: Impact of Carbohydrate Moieties in Photodynamic Therapy (PDT). Anti-Cancer Agents in Medicinal Chemistry, 2008. 8(3): p. 241-268.
 
[3]  Mink, D.F.M.a.L.M., J. Chem. Ed., 1996. 73: p. 1180.
 
[4]  Falk, J.E., Porphyrins and Metalloporphyrins. Elsevier, New York, 1975.
 
[5]  Loupy A, P.A., Hamelin J, Texier-Boullet F, Jacquault P and Mathé D., Synth. Rev., 1998: p. 1213-1234.
 
[6]  Alexandre F-R, D.L., Frère S, Testard A and Thiéry V., Mol. Diversity 2003. 7: p. 237-280.
 
[7]  Polshettiwar, V.V., R. S., Acc. Chem. Res., 2008. 41: p. 629.
 
[8]  Rocha Gonsalves, A.M.d.A.V., J. M. T. B.; Pereira, M. M., J. Heterocyclic Chem. , 1991. 28: p. 286.
 
[9]  Liu S Q, S.H.R., Sun Z T, Xu Ji Q and Li D M, Synth. Commun., 2000. 30: p. 2009.
 
[10]  Zhi-Cheng Sun, Y.-B.S., Yang Zhou, Xu-Feng Song and Kai Li Synthesis, Characterization and Spectral Properties of Substituted Tetraphenylporphyrin Iron Chloride Complexes Molecules 2011. 16: p. 2960-2970.
 
[11]  Vogler., K.G., Inorg Chem, 1994. 33: p. 314-318.